Charlotte explains why now is the right time for her to take the role, and gives her thoughts on the criticism the team have received over their fitness following an Ashes drubbing in Australia.
She also pays tribute to outgoing captain Heather Knight, and talks about what her approach will be to coaching the side.
Watch every episode of the Sky Sports Cricket Podcast on YouTube here: Sky Sports Cricket Podcast on YouTube
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You can listen to the Sky Sports Cricket Podcast on your smart speaker by saying "ask Global Player to play Sky Sports Cricket Podcast".
Join in the debate on Twitter @SkyCricket.
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